Chemistry

CHEMISTRY BY MARYE ANNE FOX Department of Chemistry University of Texas, Austin Austin, Texas The prediction of ab initio calculations that a C 18 cyclocarbon would possess alternating single and triple bonds seems to be verified in a recent study, which reports the laser flash pyrolysis of a well-characterized precursor to the title compound. Structural evidence for its formation via a retro-Diels-Alder reaction of an appropriate [18] annulene is presented. F. Diederich, Y Rubin, C.B. Knob

Marye Anne Fox
Nov 26, 1989

CHEMISTRY

BY MARYE ANNE FOX
Department of Chemistry
University of Texas, Austin
Austin, Texas

The prediction of ab initio calculations that a C 18 cyclocarbon would possess alternating single and triple bonds seems to be verified in a recent study, which reports the laser flash pyrolysis of a well-characterized precursor to the title compound. Structural evidence for its formation via a retro-Diels-Alder reaction of an appropriate [18] annulene is presented.

F. Diederich, Y Rubin, C.B. Knobler, R.L. Whetten, et al., "All-carbon molecules: evidence for the generation of cyclo[l 8]carbon from a stable organic precursor," Science, 245, 1088-90, 8 September 1989. (University of California, Los Angeles)

A novel intermediary state of matter, a helical smectic A* mesophase, has been discovered during the search for new ferroelectric liquid crystals. This layered phase shows a high degree of chirality and possesses relatively large molecular fluctuations. Since it is miscible with a classical smectic...

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